Rare Ag···H-B interactions in coordination polymers
Carbaborane C-H groups are acidic and so are able to form hydrogen bonding interactions as donors. This can be exploited in the use of carbaboranes as coordinating anions that can be involved in agostic interactions with diverse metal centres. Agostic and electrostatic interactions for Ag···H-B are very rare.
In this advance article, Luís Cunha-Silva and Michaele Hardie report the […]